❄️ Freeze-Thaw Resistance of Concrete

Construction PN-B-06250 / CEN/TS 12390-9

In short

Testing concrete resistance to cyclic freezing and thawing. Direct method (Polish) or CF/CDF (European) with assessment of mass loss and strength decrease. The test is performed according to PN-88/B-06250 pkt. 5.13 / CEN/TS 12390-9:2016; Freezing temperature: -18 ± 2°C (PN-B-06250) / -20°C (CEN/TS). The procedure comprises 11 steps (about 43 days 2 h 40 min–91 days 2 h 40 min in total); it is used for: Design of concrete pavements for roads and airports, Assessment of bridge and viaduct concrete durability, Quality control of concrete in exposure classes XF1–XF4 (PN-EN 206).

At a glance

  • Standard: PN-88/B-06250 pkt. 5.13 / CEN/TS 12390-9:2016
  • Category: Construction
  • Procedure steps: 11
  • Total time of stages: 43 days 2 h 40 min–91 days 2 h 40 min
  • Freezing temperature: -18 ± 2°C (PN-B-06250) / -20°C (CEN/TS)
  • Thawing temperature: +18 ± 2°C (PN-B-06250) / +20°C (CEN/TS)
  • Number of cycles: F25–F300 (PN-B-06250) / 28 (CDF) / 56 (CF)

Overview

Freeze-thaw resistance of concrete is a key durability characteristic in the climate of Poland and Central Europe, where concrete structures are exposed to dozens of freeze-thaw cycles annually. Testing involves subjecting concrete specimens to repeated cycles of freezing (at -18°C) and thawing (in water at +18–20°C) and assessing the resulting damage.

In Poland, two main methods are used. The direct method (Polish) per PN-88/B-06250 involves subjecting 100×100×100 mm cubic specimens to a specified number of freeze-thaw cycles (F25, F50, F100, F150, F200, F300) and comparing their compressive strength with reference specimens (stored in water). Concrete is frost-resistant if strength decrease does not exceed 20% and mass loss does not exceed 5%.

The European method CEN/TS 12390-9 (CF/CDF) assesses resistance of concrete surface to scaling under frost action. In CF method, specimen is immersed in deionized water and subjected to 56 freeze-thaw cycles. In CDF method — in 3% NaCl solution and 28 cycles. Assessment criterion is surface mass loss (scaling) in g/m² — typical requirement: ≤1500 g/m² after 28 CDF cycles.

Concrete freeze-thaw resistance depends mainly on air void structure — key parameter is spacing factor L̄ (≤0.20 mm) and air content (4–7%). Therefore, air-entraining admixtures are used in frost-resistant concretes, creating fine, uniformly distributed air voids acting as pressure buffers for freezing water.

Method principle

Direct method (PN-B-06250): Water-saturated concrete specimens are frozen in freezing chamber at -18 ± 2°C for 4 h, then thawed in water at +18 ± 2°C for 4 h (1 cycle = 8 h). After specified number of cycles (e.g., 150), compressive strength is compared with reference specimens. CDF method (CEN/TS 12390-9): Specimen surface is immersed in 3% NaCl solution to 3 mm depth. Cycle: freezing from +20°C to -20°C over 12 h and thawing to +20°C over 12 h. After 7, 14, 21 and 28 cycles, scaled concrete particles are collected and weighed.

Applications

Key parameters

ParameterValue
Freezing temperature-18 ± 2°C (PN-B-06250) / -20°C (CEN/TS)
Thawing temperature+18 ± 2°C (PN-B-06250) / +20°C (CEN/TS)
Number of cyclesF25–F300 (PN-B-06250) / 28 (CDF) / 56 (CF)
Specimen dimensions100×100×100 mm (PN-B-06250) / 150×150×50 mm (CDF)
Criterion (Polish method)Rc decrease ≤ 20%, mass loss ≤ 5%
Criterion (CDF)Scaling ≤ 1500 g/m² after 28 cycles

Standard

Standard number
PN-88/B-06250 pkt. 5.13 / CEN/TS 12390-9:2016
Title (PL)
Beton zwykły — Mrozoodporność / Badania betonu stwardniałego — Część 9: Odporność na zamrażanie-rozmrażanie — Złuszczanie
Title (EN)
Normal concrete — Frost resistance / Testing hardened concrete — Part 9: Freeze-thaw resistance — Scaling

Step-by-step procedure

  1. Specimen preparation

    Prepare 12 specimens 100×100×100 mm (Polish method) or 5 specimens 150×150×50 mm (CDF). Cure 28 days in water 20 ± 2°C.

    ⏱ Time: 28 days • 🌡 Temperature: 20 ± 2°C

  2. Series division

    Polish method: 6 frozen + 6 reference specimens (in water). CDF method: 5 test specimens + reference specimens.

    ⏱ Time: 10 min

  3. Water saturation

    Polish method: immerse specimens in water for 7 days. CDF method: seal sides with resin/foil, capillary saturate specimens in 3% NaCl.

    ⏱ Time: 7 days

  4. Initial measurements

    Weigh all specimens. CDF method: measure container mass with solution. Record dimensions.

    ⏱ Time: 15 min

  5. Cyclic freezing-thawing

    Polish method: 4 h freezing (-18°C) + 4 h thawing (water +18°C) = 1 cycle. CDF method: 12 h cooling to -20°C + 12 h heating to +20°C.

    ⏱ Time: 8–56 days

  6. Intermediate control (CDF)

    After 7, 14, 21 and 28 cycles: collect scaled particles from solution by filtering, dry at 105°C, weigh. Replenish solution.

    ⏱ Time: 1 h/measurement • 🌡 Temperature: 105°C

  7. Specimen inspection (Polish method)

    After every 25 cycles: visual inspection — no cracks, delamination. Weighing — mass loss ≤5%.

    ⏱ Time: 15 min

  8. Final strength testing

    Polish method: after reaching target cycle number — test compressive strength of frozen and reference specimens.

    ⏱ Time: 1 h

  9. Calculations

    Polish method: ΔRc = (Rc_ref - Rc_frozen)/Rc_ref × 100% ≤ 20%. CDF method: scaling Σmn/A [g/m²] ≤ 1500 after 28 cycles.

  10. Frost resistance classification

    Polish method: class F25–F300 = number of cycles without damage. CDF method: frost-resistant/non-frost-resistant per 1500 g/m² criterion.

  11. Documentation

    Report: concrete composition, curing conditions, test method, cycle number, intermediate results, strength, mass loss, classification.

Required equipment and apparatus

EquipmentExampleIndicative price
Freezing chamber (laboratory freezer)Weiss WK3 340, CTS C-40/350, Binder MK 240 — range to -30°C40 000–150 000 PLN
Thawing tank with thermostatSteel, thermostated 18–20°C, capacity min. 100 L3 000–10 000 PLN
Compression testing pressControls Automax, Matest C070 — for comparing Rc of frozen and ref. specimens80 000–250 000 PLN
Laboratory balance 10 kgRadwag WLC 10/A2, accuracy 0.1 g2 000–5 000 PLN
CDF containers (European method)Steel or plastic, with sealing frame, per CEN/TS 12390-9200–600 PLN/pc
Laboratory ovenPOL-EKO SLW 115, for drying scaled particles5 000–12 000 PLN
Thermometer with data loggerTesto 176 T2, Pt100 sensor, 10 min recording — chamber temperature monitoring1 500–4 000 PLN

Reagents, media and consumables

ReagentCASDetails
Sodium chloride (NaCl)7647-14-5For preparing 3% solution in CDF method, analytical grade purity
Deionized waterFor CF method and for preparing NaCl solution in CDF method
Epoxy resinFor sealing CDF specimen side surfaces (only test surface exposed)
Aluminum foilFor wrapping CDF specimen sides as moisture barrier (alternative to resin)
Butyl rubber (gasket)For sealing CDF container edge with specimen

Health and safety (OHS)

Frequently asked questions

Which standard describes this test?

The test is performed according to PN-88/B-06250 pkt. 5.13 / CEN/TS 12390-9:2016 — “Normal concrete — Frost resistance / Testing hardened concrete — Part 9: Freeze-thaw resistance — Scaling”.

How does this method work?

Direct method (PN-B-06250): Water-saturated concrete specimens are frozen in freezing chamber at -18 ± 2°C for 4 h, then thawed in water at +18 ± 2°C for 4 h (1 cycle = 8 h). After specified number of cycles (e.

What is the measuring range and accuracy?

Freezing temperature: -18 ± 2°C (PN-B-06250) / -20°C (CEN/TS); Thawing temperature: +18 ± 2°C (PN-B-06250) / +20°C (CEN/TS); Number of cycles: F25–F300 (PN-B-06250) / 28 (CDF) / 56 (CF); Specimen dimensions: 100×100×100 mm (PN-B-06250) / 150×150×50 mm (CDF).

How long does the test take?

The times given for the individual stages add up to approximately 43 days 2 h 40 min–91 days 2 h 40 min. The procedure comprises 11 steps.

What equipment is required?

Freezing chamber (laboratory freezer), Thawing tank with thermostat, Compression testing press, Laboratory balance 10 kg, CDF containers (European method), Laboratory oven, Thermometer with data logger. Indicative cost of the core instrument (Freezing chamber (laboratory freezer)): 40 000–150 000 PLN.

Where is this test used?

Design of concrete pavements for roads and airports; Assessment of bridge and viaduct concrete durability; Quality control of concrete in exposure classes XF1–XF4 (PN-EN 206); Testing of precast concrete elements exposed to frost (paving blocks, curbs); Assessment of air-entraining admixture effectiveness; Expertise of frost damage to existing structures; Testing of architectural concrete exposed to atmospheric conditions.

What safety precautions apply?

Freezing chamber — frostbite risk, use thermal gloves and protective clothing; Handling frozen specimens — slippery, fall and bruise risk; NaCl solution — corrosive to low-grade stainless steel, protect equipment; Epoxy resin — sensitizing, use gloves and ventilation; Compression press — crushing hazard, fragments during specimen failure.

Which laboratory can perform this test?

The test is performed by laboratories accredited to ISO/IEC 17025. On LabCoda you can find them by the standard number PN-B-06250 / CEN/TS 12390-9.

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